Multiplayer Characters:

Two, three or four agents or enemies will exercise their license to kill
in Multi-player mode. If two agents are hunting, the screen will be split
in half horizontally, but in the three and four agent modes, it will be
quartered. Be aware that you can only battle against other human opponents
and not against a CPU foe in the Multi-player mode.

CHARACTERS
From the start you'll be able to select from eight different characters
from the GoldenEye affair:

James Bond

Alec Trevelyan

Xenia Onatopp

Natalya Simonovna

General Ouromov

Boris Grishenko

Valentin Zukovsky

Dimitri Mishkin

 

After you finish the entire GoldenEye mission (in single player Mission
mode), you'll open up a bunch of hidden players, including Janus
mercenaries and guest villains like Jaws, Oddjob, Mayday and Baron Samedi.

Oddjob

Baron Samedi

Jaws

Mayday

 

The different characters are all fairly similar in performance, but a
couple are different.

Oddjob
He is the smallest character available in the Multi-player mode. When he
crouches, he can be a very difficult target to hit.

Jaws
The giant Jaws is so tall he will often fire over the head of his target
when at close range.

Baron Samedi
He is also fairly tall, which makes him a slightly larger target than
average.

Boris
Boris is another short character, but not as drastically height impaired as
Oddjob. He's also fairly skinny which makes him a harder target.

Siberian Special Forces
This character wears a grey colored camouflage uniform that can make him
difficult to see in the levels with concrete walls, like the Basement and
the Complex. Stand still and from a distance, you will be a very difficult
target.

Moonraker Scientist
The female Moonraker scientist is also a little smaller than your average
character, which can make her tougher to hit.

In multiplayer, I usually use Boris, Oddjob, Arctic Commando, Scientist
(Male), Siberian Special Forces, Jungle Commando, and last but not least